DLQ001 15 ppm Diesel Sulfur Precision Demonstration

Fuels Regulatory Streamlining (Non-Substantive Change)

Copy of Copy of draft-diesel-sulfur-test-method-spreadsheet-example-5-10-2022.xlsx

Fuels Regulatory Streamlining

OMB: 2060-0731

Document [xlsx]
Download: xlsx | pdf

Overview

15 ppm S Precision
15 ppm S Accuracy
500 ppm S Precision
500 ppm S Accuracy
EX - 15 ppm S Precision
EX - 15 ppm S Accuracy
EX - 500 ppm S Precision
EX - 500 ppm S Accuracy


Sheet 1: 15 ppm S Precision

15 ppm Diesel Sulfur Precision Demonstration [DLQ001:OMB # 2060-0731, Expires 1/31/2024]. This collection of information is approved by OMB under the Paperwork Reduction Act, 44 U.S.C. 3501 et seq. OMB Control No 2060-0731. Responses to this collection of information are voluntary 1090 CFR 1360 through 1090 1365. An agency may not conduct or sponsor, and a person is not required to respond to, a collection of information unless it displays a currently valid OMB control number. The public reporting and recordkeeping burden for this collection of information is estimated to average 180 hours per response. Send comments on the Agency’s need for this information, the accuracy of the provided burden estimates and any suggested methods for minimizing respondent burden to the Regulatory Support Division Director, U.S. Environmental Protection Agency (2821T), 1200 Pennsylvania Ave., NW, Washington, D.C. 20460. Include the OMB control number in any correspondence. Do not send the completed form to this address.
Test Method
Name of Method:
Organization ID No. (as in ASTM D XXXX-XX):
Laboratory Identification
Laboratory Name:
Laboratory Street Address:
Laboratory City:
Laboratory State:
Laboratory Zip code:
Laboratory Contact Person:
Laboratory Contact Phone Number
Laboratory Contact Facsimile Number
Laboratory Contact E-mail Address
Confidential Business Information Claim. A company may assert a business confidentiality claim covering the information contained in this submission. If no such claim is made the information may be made available to the public by EPA without further notice. All questions of confidentiality will be handled pursuant to 40 CFR Part 2. Is confidentiality claimed for the information in this submission? (Note: Please answer by typing "Yes" or "No" in the adjacent cell.)
15 ppm Sulfur Precision Criterion (§1090.1365(b)) - a standard deviation less than 0.72 ppm, computed from the results of a minimum of 20 repeat tests made over 20 days on samples taken from a single homogenous commerically available diesel fuel with a sulfur range of 5 to 15 ppm. A lab facility may exclude a given sample or test result only if the exclusion is for a valid reason under good laboratory practices and it maintains records regarding the sample and test results and the reason for excluding them.
Is 15 ppm Sulfur Precision Criterion Met? REQUIRED DATA MISSING
standard deviation REQUIRED DATA MISSING
Laboratory Test Identification Number Date Time Test Result (ppm) Data Entry QC Check on Test Result




DATA REQUIRED IN CELL D20




DATA REQUIRED IN CELL D21




DATA REQUIRED IN CELL D22




DATA REQUIRED IN CELL D23




DATA REQUIRED IN CELL D24




DATA REQUIRED IN CELL D25




DATA REQUIRED IN CELL D26




DATA REQUIRED IN CELL D27




DATA REQUIRED IN CELL D28




DATA REQUIRED IN CELL D29




DATA REQUIRED IN CELL D30




DATA REQUIRED IN CELL D31




DATA REQUIRED IN CELL D32




DATA REQUIRED IN CELL D33




DATA REQUIRED IN CELL D34




DATA REQUIRED IN CELL D35




DATA REQUIRED IN CELL D36




DATA REQUIRED IN CELL D37




DATA REQUIRED IN CELL D38




DATA REQUIRED IN CELL D39

Sheet 2: 15 ppm S Accuracy

15 ppm Diesel Sulfur Accuracy Demonstration [DLQ001:OMB # 2060-0731 EPA ICR number 2607.02: Expires 1/31/2024]
Test Method
Name of Method: 0
Organization ID No. (as in ASTM D XXXX-XX): 0
Laboratory Identification
Laboratory Name: 0
Laboratory Street Address: 0
Laboratory City: 0
Laboratory State: 0
Laboratory Zip code: 0
Laboratory Contact Person: 0
Laboratory Contact Phone Number 0
Laboratory Contact Facsimile Number 0
Laboratory Contact E-mail Address 0
Confidential Business Information Claim. A company may assert a business confidentiality claim covering the information contained in this submission. If no such claim is made the information may be made available to the public by EPA without further notice. All questions of confidentiality will be handled pursuant to 40 CFR Part 2. Is confidentiality claimed for the information in this submission? (Note: Please answer by typing "Yes" or "No" in the adjacent cell.)
10 to 20 ppm Accuracy Criterion §1090.1365(c)(3)(ii) - the arithmetic average of a continuous series of at least 10 tests performed on a commercially available gravimetric sulfur standard in the range of 10 to 20 ppm sulfur shall not differ from the accepted reference value (ARV) of that standard by more than 0.54 ppm. Individual test results shall be compensated for any known chemical interferences.



Accuracy Criterion for 10-20 ppm




gravimetric sulfur standard




Is 10-20 ppm Sulfur Accuracy Criterion Met? REQUIRED DATA MISSING




Arithmetic Average (ppm) REQUIRED DATA MISSING




Vendor Name of Gravimetric Standard





Lot Identification Number of Gravimetric Standard
Concentration QC Check on ARV



Accepted Reference Value (ARV) of Gravimetric Standard (ppm)
ARV TOO LOW IN CONCENTRATION



Difference between Arithmetic Average and ARV of Gravimetric Standard REQUIRED DATA MISSING




Laboratory Test Identification Number Date Time Test Result (ppm) Data Entry QC Check on Test Result







DATA REQUIRED IN CELL D26







DATA REQUIRED IN CELL D27







DATA REQUIRED IN CELL D28







DATA REQUIRED IN CELL D29







DATA REQUIRED IN CELL D30







DATA REQUIRED IN CELL D31







DATA REQUIRED IN CELL D32







DATA REQUIRED IN CELL D33







DATA REQUIRED IN CELL D34







DATA REQUIRED IN CELL D35




Sheet 3: 500 ppm S Precision

500 ppm Diesel Sulfur Precision Demonstration [DLQ001:OMB # 2060-0731, EPA ICR number 2607.02: Expires 1/31/2024]
Test Method
Name of Method:
Organization ID No. (as in ASTM D XXXX-XX):
Laboratory Identification
Laboratory Name:
Laboratory Street Address:
Laboratory City:
Laboratory State:
Laboratory Zip code:
Laboratory Contact Person:
Laboratory Contact Phone Number
Laboratory Contact Facsimile Number
Laboratory Contact E-mail Address
Confidential Business Information Claim. A company may assert a business confidentiality claim covering the information contained in this submission. If no such claim is made the information may be made available to the public by EPA without further notice. All questions of confidentiality will be handled pursuant to 40 CFR Part 2. Is confidentiality claimed for the information in this submission? (Note: Please answer by typing "Yes" or "No" in the adjacent cell.)
500 ppm Sulfur Precision Criterion (§1090.1365(b) - a standard deviation less than 11.5 ppm, computed from the results of a minimum of 20 repeat tests made over 20 days on samples taken from a single homogenous commerically available diesel fuel with a sulfur range of 350 to 500 ppm. A lab facility may exclude a given sample or test result only if the exclusion is for a valid reason under good laboratory practices and it maintains records regarding the sample and test results and the reason for excluding them.
Is 500 ppm Sulfur Precision Criterion Met? REQUIRED DATA MISSING
standard deviation REQUIRED DATA MISSING
Laboratory Test Identification Number Date Time Test Result (ppm) Data Entry QC Check on Test Result




DATA REQUIRED IN CELL D20




DATA REQUIRED IN CELL D21




DATA REQUIRED IN CELL D22




DATA REQUIRED IN CELL D23




DATA REQUIRED IN CELL D24




DATA REQUIRED IN CELL D25




DATA REQUIRED IN CELL D26




DATA REQUIRED IN CELL D27




DATA REQUIRED IN CELL D28




DATA REQUIRED IN CELL D29




DATA REQUIRED IN CELL D30




DATA REQUIRED IN CELL D31




DATA REQUIRED IN CELL D32




DATA REQUIRED IN CELL D33




DATA REQUIRED IN CELL D34




DATA REQUIRED IN CELL D35




DATA REQUIRED IN CELL D36




DATA REQUIRED IN CELL D37




DATA REQUIRED IN CELL D38




DATA REQUIRED IN CELL D39

Sheet 4: 500 ppm S Accuracy

500 ppm Diesel Sulfur Accuracy Demonstration [DLQ001:OMB # 2060-0731, EPA ICR number 2607.02: Expires 1/31/2024]







Test Method
Name of Method: 0
Organization ID No. (as in ASTM D XXXX-XX): 0
Laboratory Identification
Laboratory Name: 0
Laboratory Street Address: 0
Laboratory City: 0
Laboratory State: 0
Laboratory Zip code: 0
Laboratory Contact Person: 0
Laboratory Contact Phone Number 0
Laboratory Contact Facsimile Number 0
Laboratory Contact E-mail Address 0
Confidential Business Information Claim. A company may assert a business confidentiality claim covering the information contained in this submission. If no such claim is made the information may be made available to the public by EPA without further notice. All questions of confidentiality will be handled pursuant to 40 CFR Part 2. Is confidentiality claimed for the information in this submission? (Note: Please answer by typing "Yes" or "No" in the adjacent cell.)
450 to 500 ppm Accuracy Criterion §1090.1365(c)(3)(ii) - the arithmetic average of a continuous series of at least 10 tests performed on a commercially available gravimetric sulfur standard in the range of 450 to 500 ppm sulfur shall not differ from the accepted reference value (ARV) of that standard by more than 8.65 ppm. Individual test results shall be compensated for any known chemical interferences.



Accuracy Criterion for 450-500 ppm




gravimetric sulfur standard




Is 450-500 ppm Sulfur Accuracy Criterion Met? REQUIRED DATA MISSING




Arithmetic Average (ppm): REQUIRED DATA MISSING




Vendor Name of Gravimetric Standard:





Lot Identification Number of Gravimetric Standard:
Concentration QC Check on ARV



Accepted Reference Value (ARV) of Gravimetric Standard (ppm):
ARV TOO LOW IN CONCENTRATION



Difference between Arithmetic Average and ARV of Gravimetric Standard: REQUIRED DATA MISSING




Laboratory Test Identification Number Date Time Test Result (ppm) Data Entry QC Check on Test Result







DATA REQUIRED IN CELL D26







DATA REQUIRED IN CELL D27







DATA REQUIRED IN CELL D28







DATA REQUIRED IN CELL D29







DATA REQUIRED IN CELL D30







DATA REQUIRED IN CELL D31







DATA REQUIRED IN CELL D32







DATA REQUIRED IN CELL D33







DATA REQUIRED IN CELL D34







DATA REQUIRED IN CELL D35




Sheet 5: EX - 15 ppm S Precision

15 ppm Diesel Sulfur Precision Demonstration [DLQ001:OMB # 2060-0731, EPA ICR number 2607.02: Expires 1/31/2024]
Test Method
Name of Method: Total Sulfur in Liquid Aromatic Hydrocarbons and Their Derivatives by Oxidative and Electrochemical Detection
Organization ID No. (as in ASTM D XXXX-XX): ASTM D 6428-99
Laboratory Identification
Laboratory Name: USEPA National and Vehicle Fuels Emissions Laboratory/OAR
Laboratory Street Address: 2565 Plymouth Road, Mailcode AATSG
Laboratory City: Ann Arbor
Laboratory State: Michigan
Laboratory Zip code: 48105
Laboratory Contact Person: John Doe
Laboratory Contact Phone Number xxx-xxx-xxxx
Laboratory Contact Facsimile Number xxx-xxx-xxxx
Laboratory Contact E-mail Address [email protected]
Confidential Business Information Claim. A company may assert a business confidentiality claim covering the information contained in this submission. If no such claim is made the information may be made available to the public by EPA without further notice. All questions of confidentiality will be handled pursuant to 40 CFR Part 2. Is confidentiality claimed for the information in this submission? (Note: Please answer by typing "Yes" or "No" in the adjacent cell.) No
15 ppm Sulfur Precision Criterion (§1090.1365(b) - a standard deviation less than 0.72 ppm, computed from the results of a minimum of 20 repeat tests made over 20 days on samples taken from a single homogenous commerically available diesel fuel with a sulfur range of 5 to 15 ppm. A lab facility may exclude a given sample or test result only if the exclusion is for a valid reason under good laboratory practices and it maintains records regarding the sample and test results and the reason for excluding them.
Is 15 ppm Sulfur Precision Criterion Met? PASSED
standard deviation 0.04
Laboratory Test Identification Number Date Time Test Result (ppm) Data Entry QC Check on Test Result
######### 10/26/2004 8:00 AM 6.003 OK
######### 10/27/2004 8:05 AM 6.021 OK
######### 10/28/2004 8:03 AM 6.043 OK
######### 10/29/2004 8:05 AM 5.993 OK
######### 10/30/2004 8:05 AM 6.003 OK
######### 11/1/2004 8:03 AM 6.092 OK
######### 11/2/2004 8:03 AM 6.101 OK
######### 11/3/2004 8:03 AM 6.045 OK
######### 11/5/2004 8:00 AM 6.003 OK
######### 11/6/2004 8:00 AM 6.021 OK
######### 11/7/2004 8:02 AM 5.989 OK
######### 11/8/2004 8:00 AM 5.962 OK
######### 11/9/2004 8:00 AM 6.010 OK
######### 11/10/2004 8:00 AM 6.032 OK
######### 11/11/2004 8:15 AM 6.053 OK
######### 11/12/2004 8:00 AM 6.050 OK
######### 11/13/2004 8:07 AM 5.989 OK
######### 11/14/2004 8:00 AM 6.033 OK
######### 11/15/2004 8:00 AM 5.939 OK
######### 11/16/2004 8:20 AM 6.042 OK

Sheet 6: EX - 15 ppm S Accuracy

15 ppm Diesel Sulfur Accuracy Demonstration [DLQ001:OMB # 2060-0731, EPA ICR number 2607.02: Expires 1/31/2024]
Test Method
Name of Method: Total Sulfur in Liquid Aromatic Hydrocarbons and Their Derivatives by Oxidative and Electrochemical Detection
Organization ID No. (as in ASTM D XXXX-XX): ASTM D 6428-99
Laboratory Identification
Laboratory Name: USEPA National and Vehicle Fuels Emissions Laboratory/OAR
Laboratory Street Address: 2565 Plymouth Road, Mailcode AATSG
Laboratory City: Ann Arbor
Laboratory State: Michigan
Laboratory Zip code: 48105
Laboratory Contact Person: John Doe
Laboratory Contact Phone Number xxx-xxx-xxxx
Laboratory Contact Facsimile Number xxx-xxx-xxxx
Laboratory Contact E-mail Address [email protected]
Confidential Business Information Claim. A company may assert a business confidentiality claim covering the information contained in this submission. If no such claim is made the information may be made available to the public by EPA without further notice. All questions of confidentiality will be handled pursuant to 40 CFR Part 2. Is confidentiality claimed for the information in this submission? (Note: Please answer by typing "Yes" or "No" in the adjacent cell.) No
10 to 20 ppm Accuracy Criterion §1090.1365(c)(3)(ii) - the arithmetic average of a continuous series of at least 10 tests performed on a commercially available gravimetric sulfur standard in the range of 10 to 20 ppm sulfur shall not differ from the accepted reference value (ARV) of that standard by more than 0.54 ppm. Individual test results shall be compensated for any known chemical interferences.



Accuracy Criterion for 10-20 ppm




gravimetric sulfur standard




Is 10-20 ppm Sulfur Accuracy Criterion Met? PASSED




Arithmetic Average (ppm) 7.95




Vendor Name of Gravimetric Standard NIST




Lot Identification Number of Gravimetric Standard ALDS45678 Concentration QC Check on ARV



Accepted Reference Value (ARV) of Gravimetric Standard (ppm) 8.00 OK



Difference between Arithmetic Average and ARV of Gravimetric Standard 0.0515




Laboratory Test Identification Number Date Time Test Result (ppm) Data Entry QC Check on Test Result



######### 1/13/2005 8:00 AM 7.341 OK



######### 1/13/2005 8:05 AM 7.562 OK



######### 1/13/2005 8:10 AM 7.894 OK



######### 1/13/2005 8:15 AM 8.219 OK



######### 1/13/2005 8:20 AM 8.234 OK



######### 1/13/2005 8:25 AM 8.100 OK



######### 1/13/2005 8:30 AM 8.114 OK



######### 1/13/2005 8:35 AM 7.989 OK



######### 1/13/2005 8:40 AM 7.687 OK



######### 1/13/2005 8:45am 8.345 OK




Sheet 7: EX - 500 ppm S Precision

500 ppm Diesel Sulfur Precision Demonstration [DLQ001:OMB # 2060-0731, EPA ICR number 2607.02: Expires 1/31/2024]



Test Method



Name of Method: Standard Test Method for Sulfur in Petroleum Products by Wavelength Dispersive X-ray Fluorescence Spectrometry



Organization ID No. (as in ASTM D XXXX-XX): ASTM D 2622-03



Laboratory Identification



Laboratory Name: USEPA National and Vehicle Fuels Emissions Laboratory/OAR



Laboratory Street Address: 2565 Plymouth Road, Mailcode AATSG



Laboratory City: Ann Arbor



Laboratory State: Michigan



Laboratory Zip code: 48105



Laboratory Contact Person: John Doe



Laboratory Contact Phone Number xxx-xxx-xxxx



Laboratory Contact Facsimile Number xxx-xxx-xxxx



Laboratory Contact E-mail Address [email protected]
Confidential Business Information Claim. A company may assert a business confidentiality claim covering the information contained in this submission. If no such claim is made the information may be made available to the public by EPA without further notice. All questions of confidentiality will be handled pursuant to 40 CFR Part 2. Is confidentiality claimed for the information in this submission? (Note: Please answer by typing "Yes" or "No" in the adjacent cell.) No



500 ppm Sulfur Precision Criterion (§1090.1365(b) - a standard deviation less than 11.5 ppm, computed from the results of a minimum of 20 repeat tests made over 20 days on samples taken from a single homogenous commerically available diesel fuel with a sulfur range of 350 to 500 ppm. A lab facility may exclude a given sample or test result only if the exclusion is for a valid reason under good laboratory practices and it maintains records regarding the sample and test results and the reason for excluding them.



Is 500 ppm Sulfur Precision Criterion Met? PASSED




standard deviation 4.49




Laboratory Test Identification Number Date Time Test Result (ppm) Data Entry QC Check on Test Result



######### 10/26/2004 8:00 AM 330.023 OK



######### 10/27/2004 8:05 AM 331.234 OK



######### 10/28/2004 8:03 AM 332.897 OK



######### 10/29/2004 8:05 AM 334.598 OK



######### 10/30/2004 8:05 AM 335.998 OK



######### 11/1/2004 8:03 AM 328.359 OK



######### 11/2/2004 8:03 AM 329.062 OK



######### 11/3/2004 8:03 AM 330.108 OK



######### 11/5/2004 8:00 AM 333.730 OK



######### 11/6/2004 8:00 AM 335.092 OK



######### 11/7/2004 8:02 AM 326.340 OK



######### 11/8/2004 8:00 AM 328.903 OK



######### 11/9/2004 8:00 AM 329.863 OK



######### 11/10/2004 8:00 AM 332.998 OK



######### 11/11/2004 8:15 AM 334.001 OK



######### 11/12/2004 8:00 AM 340.100 OK



######### 11/13/2004 8:07 AM 341.102 OK



######### 11/14/2004 8:00 AM 339.887 OK



######### 11/15/2004 8:00 AM 338.776 OK



######### 11/16/2004 8:20 AM 340.002 OK




Sheet 8: EX - 500 ppm S Accuracy

500 ppm Diesel Sulfur Accuracy Demonstration [DLQ001:OMB # 2060-0731, EPA ICR number 2607.02: Expires 1/31/2024]
Test Method
Name of Method: Standard Test Method for Sulfur in Petroleum Products by Wavelength Dispersive X-ray Fluorescence Spectrometry
Organization ID No. (as in ASTM D XXXX-XX): ASTM D 2622-03
Laboratory Identification
Laboratory Name: USEPA National and Vehicle Fuels Emissions Laboratory/OAR
Laboratory Street Address: 2565 Plymouth Road, Mailcode AATSG
Laboratory City: Ann Arbor
Laboratory State: Michigan
Laboratory Zip code: 48105
Laboratory Contact Person: John Doe
Laboratory Contact Phone Number xxx-xxx-xxxx
Laboratory Contact Facsimile Number xxx-xxx-xxxx
Laboratory Contact E-mail Address [email protected]
Confidential Business Information Claim. A company may assert a business confidentiality claim covering the information contained in this submission. If no such claim is made the information may be made available to the public by EPA without further notice. All questions of confidentiality will be handled pursuant to 40 CFR Part 2. Is confidentiality claimed for the information in this submission? (Note: Please answer by typing "Yes" or "No" in the adjacent cell.) No
450 to 500 ppm Accuracy Criterion §1090.1365(c)(3)(ii) - the arithmetic average of a continuous series of at least 10 tests performed on a commercially available gravimetric sulfur standard in the range of 450 to 500 ppm sulfur shall not differ from the accepted reference value (ARV) of that standard by more than 8.65 ppm. Individual test results shall be compensated for any known chemical interferences.



Accuracy Criterion for 450-500 ppm




gravimetric sulfur standard




Is 450-500 ppm Sulfur Accuracy Criterion Met? PASSED




Arithmetic Average (ppm): 150.56




Vendor Name of Gravimetric Standard: NIST




Lot Identification Number of Gravimetric Standard: AMD4567 Concentration QC Check on ARV



Accepted Reference Value (ARV) of Gravimetric Standard (ppm): 151.00 OK



Difference between Arithmetic Average and ARV of Gravimetric Standard: 0.435699999999969




Laboratory Test Identification Number Date Time Test Result (ppm) Data Entry QC Check on Test Result



######### 1/13/2005 8:00 AM 150.003 OK



######### 1/13/2005 8:05 AM 150.030 OK



######### 1/13/2005 8:10 AM 150.100 OK



######### 1/13/2005 8:15 AM 149.650 OK



######### 1/13/2005 8:20 AM 148.500 OK



######### 1/13/2005 8:25 AM 150.000 OK



######### 1/13/2005 8:30 AM 150.100 OK



######### 1/13/2005 8:35 AM 151.910 OK



######### 1/13/2005 8:40 AM 152.130 OK



######### 1/13/2005 8:45am 153.220 OK



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